Diastereoselective Intramolecular Cyanoamidation with Alkenes
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چکیده
منابع مشابه
Cobalt-Catalyzed Enantio- and Diastereoselective Intramolecular Hydroacylation of Trisubstituted Alkenes.
Enantio- and diastereoselective synthesis of trans-2,3-disubstituted indanones is achieved by intramolecular hydroacylation of 2-alkenylbenzaldehydes bearing trisubstituted alkenyl groups under cobalt-chiral diphosphine catalysis. Notably, a high level of enantioselectivity is induced regardless of the stereochemistry (E/Z ratio) of the alkenyl group of the starting material. Deuterium-labeling...
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2016
ISSN: 1434-193X
DOI: 10.1002/ejoc.201601283